EPR / DNP / NMR Literature Blog

Balancing dipolar and exchange coupling in biradicals to maximize cross effect dynamic nuclear polarization #DNPNMR

September 25, 2020 - Equbal, Asif, Kan Tagami, and Songi Han. “Balancing Dipolar and Exchange Coupling in Biradicals to Maximize Cross Effect Dynamic Nuclear Polarization.

Heteronuclear DNP of 1H and 19F nuclei using BDPA as a polarizing agent #DNPNMR

August 5, 2020 - Gennaro, Antonio, Alexander Karabanov, Alexey Potapov, and Walter Köckenberger. “Heteronuclear DNP of 1H and 19F Nuclei Using BDPA as a Polarizing Agent.

Study of electron spectral diffusion process under DNP conditions by ELDOR spectroscopy focusing on the 14N Solid Effect #DNPNMR

July 24, 2020 - Ramirez Cohen, Marie, Akiva Feintuch, Daniella Goldfarb, and Shimon Vega. “Study of Electron Spectral Diffusion Process under DNP Conditions by ELDOR Spectroscopy Focusing on the 14N Solid Effect.

Nitroxide Derivatives for Dynamic Nuclear Polarization in Liquids: The Role of Rotational Diffusion #DNPNMR

July 8, 2020 - Levien, M., M. Hiller, I. Tkach, M. Bennati, and T. Orlando. “Nitroxide Derivatives for Dynamic Nuclear Polarization in Liquids: The Role of Rotational Diffusion.

Relaxation Mechanisms #DNPNMR #EPR

May 20, 2020 - This is an excellent review and summary on different relaxation mechanisms observed in EPR spectroscopy. Understanding EPR relaxation is crucial to understand the DNP process.

A calibration-based approach to real-time in-vivo monitoring of pyruvate C1 and C2 polarization using the J_CC spectral asymmetry #DNPNMR

May 18, 2020 - To measure the degree of polarization induced by the DNP process, one possibility is to calculate the ratio of the microwave OFF signal to microwave ON signal (neglecting depolarization under MAS conditions).